The 35-year-old actress, who plays Taylor Stappord on the comedy-drama, will reappear after making a guest appearance last year, reported Deadline.
Brown starred in the first season, before her character moved to Washington DC with her husband.
She recently recurred in USA Network's Graceland, in addition to guest appearances on 'The Mentalist' and 'Revenge'.
Gilles Marini was previously confirmed to be promoted to series regular status on 'Devious Maids' as Sebastien.
The third season of the Lifetime show will air later this year.
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