The company said in a statement to Shanghai's stock exchange that it would buy 13 Boeing 787-9 passenger jets and six 737-8s, citing the continued "rapid growth" in China's travel market as incomes rise.
It plans to issue 15 billion yuan (USD 2.18 billion) in bonds to help fund the deal.
Chinese airlines have seen booming business in recent years, rushing to expand their fleets and route networks amid growth that the International Air Transport Association (IATA) predicts will take China past the United States to become the world's largest air-travel market by 2024.
HNA is a sprawling conglomerate with interests in aviation and tourism.
Last year alone, HNA purchased Brazil's third largest airline Azul, Swiss airline catering company gategroup, and stakes airline Virgin Australia and Portuguese national airline TAP.
A unit of privately held HNA announced in October plans to buy the aircraft leasing business of US-based CIT Group Inc. For USD 10 billion.
The Chinese government has encouraged companies to invest overseas to open up new markets.
The government has since reversed course, denouncing "irrational" investment abroad and putting restrictions on fund outflows.
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