Xi backed using Australia, particularly Tasmania, as a gateway to the frozen continent in an agreement with Prime Minister Tony Abbott in the state's capital Hobart, where China's Antarctic programme's flagship Xue Long is docked.
The memorandum of understanding also reaffirmed China's vow to respect the icy region as a natural reserve that will not be exploited, while committing the two countries to collaborate on scientific projects.
Approximately 30 nations operate permanent research stations in Antarctica including the US, Russia, Australia, Britain, France and Argentina, with Hobart, which is home to the Australian Antarctic Division, a key shipping gateway to the area.
The inking capped a whirlwind trip to the so-called Apple Isle by the Chinese leader, who has visited every other Australian state and territory and joked Monday that he should receive a certificate for his travels across the country.
"Your visit to Hobart is a significant step in the relationship between us; one which has been built on a spirit of friendship and mutual respect," it said.
Xi said he chose to visit the southern state following the G20 summit in Brisbane on the weekend after receiving a letter from primary school students in Launceston in the state's north.
"In their letter, they describe Tasmania's unique products and beautiful scenery, they hand-wrote the letter in Chinese," Xi said in his address to the Australian parliament in Canberra yesterday.
Andy Muller, Scotch Oakburn College's principal, told AFP his students were thrilled about their meeting with the president and that it was "one of the most exciting days of their lives".
"The president invited them to come to China to visit, sightsee and study, and the students are all very motivated to continue with their Chinese and go over there.
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