"Fifth Harmony", the popular American girl group, will play a special version of "Worth It" at the ceremony, reported Billboard.
Brown, 26, Pitbull, 34 and Fifth Harmony join previously announced performers Mariah Carey, Kelly Clarkson, Fall Out Boy featuring Wiz Khalifa, Nicki Minaj and David Guetta, Britney Spears and Iggy Azalea.
The 2015 BBMAs will air on May 17 on ABC from Las Vegas.
