Economic ties will also dominate talks between Hollande and his South African counterpart Jacob Zuma today, with the two nations due to sign accords including one on developing South Africa's nuclear power.
France will also grant energy-strapped South Africa's power giant Eskom a loan of 100 million euros (USD 130 million) for the construction of a solar power station and a wind farm.
Hollande flew into Johannesburg early today and was due to hold a meeting with Zuma shortly afterwards.
France is still heavily involved in security and peacekeeping in its former colonies where it has often stepped in militarily.
However Hollande has tried hard to shrug off the negative image of "France-Afrique", a term used to describe the secretive use of political and economic influence between elites in France and former colonies.
France, a "big player" in Africa, is trying to "get South Africa to be playing a stronger role in continental security efforts," said David Hornsby, a lecturer at the University of the Witwatersrand.
"And the only one really who is established... Is South Africa. There is no way France can have a strategy (for Africa) ignoring South Africa," he said.
The two countries have often disagreed over how to tackle conflicts such as those in Libya and Ivory Coast.
However French officials say Hollande has maintained close contact with Zuma over the situation in Mali, where French forces intervened against Islamist groups this year.
South Africa pulled its troops out of the CAR in March after 15 soldiers were killed as the Seleka rebel coalition seized power, and French forces helped with their evacuation.
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