The 36-year-old actress said she was so much in awe of Keaton that she could not speak a word in front of her, reported ET online.
"I was at something recently and Diane Keaton was there and I got a little tongue tied," Williams said.
The actress said her latest film "Manchester by the Sea" said the movie seems to be resonating with audiences.
"It is actually full of unexpected hilarity, there's moments in the movie that you can't believe it, you just find yourself laughing. It's so much like life, these sort of good and bad things happen in concert with each other," she said.
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