Skipper Alastair Cook got out in the day's final over after scoring a dogged 54.
At stumps, Joe Root was batting on 5, with his team needing another 318 runs for a win.
Earlier, India were all out for 204 in their second innings.
Brief scores:
India 1st innings: 455 & 8 for no loss in 6 overs.
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England 1st Innings: 255 all out in in 102.5 overs.
India 2nd innings: 204 in 63.1 overs (Virat Kohli 81; S Broad 4/33)
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