Dijsselbloem also warned today that negotiations for Britain's departure from the EU would take "a lot longer than two years" -- the estimated timetable written into the EU treaties.
Dijsselbloem spoke after an interview by Boris Johnson with Czech daily Hospodarske Noviny in which the British foreign minister reportedly said Britain would "probably" have to leave the European customs union but still have "free trade" with EU states.
"He's saying things that are intellectually impossible, politically unavailable," Dijsselbloem, who is the Dutch finance minister and head of the eurozone finance ministers group, told the BBC.
At the conference, his spokesman said he told delegates: "Negotiations are hugely complex... They are going to take a lot longer than two years".
Prime Minister Theresa May addressed parliament in defensive mode today, following a leaked report from a consultancy saying the government had no overall plan for Brexit.
"Yes we do have a plan," she told MPs, but then refused to reveal what it was in any detail, saying this would undermine Britain's negotiating position.
He also said that the British and EU economies would both be in "a worse situation" after Brexit.
Britain voted to leave the European Union in a referendum in June and May has said she will trigger Article 50 -- the formal procedure for departure -- by the end of March 2017 at the latest.
One of the key factors behind the Brexit vote was the influx of hundreds of thousands of citizens of other EU states into Britain every year to find work.
A survey by NatCen Social Research published today found Britons overwhelmingly want to maintain free trade with the European Union after Brexit while controlling EU immigration.
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