From April this year, the Silicon Valley headquartered firm will restructure its tax policy so that revenue generated from its largest advertisers displaying content on Facebook will be routed through the UK rather than Ireland.
The change, which will generate higher taxable profits in Britain, follows accusations that the US firm was paying far too little tax in the country.
"On Monday we will start notifying large UK customers that from the start of April they will receive invoices from Facebook UK and not Facebook Ireland," Facebook said in an internal post seen by the BBC.
"What this means in practice is that UK sales made directly by our UK team will be booked in the UK, not Ireland.
Facebook UK will then record the revenue from these sales.
"In light of changes to tax law in the UK, we felt this change would provide transparency to Facebook's operations in the UK.
Smaller business sales where advertising is booked online, with little or no Facebook staff intervention, will still be routed through Ireland, which will remain the company's international headquarters.
Corporation tax is levied at 20 per cent in the UK on the profits a business makes.
As the latest changes will be put in place from April, Facebook's first higher tax bill will be paid in 2017.
At this stage, it is not clear how much tax Facebook will pay as it is not under regulatory obligation to reveal the size of its UK business until it reaches 10 per cent of its global operations, which generate revenues of nearly 18 billion dollars a year.
Before the new structure, Facebook's UK revenues were based on a fee payment from Facebook Ireland, which meant that its actual sales here did not affect its tax bill.
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