Ukraine and Russia -- two ex-Soviet neighbours that are now sworn foes -- agreed to the armistice Wednesday with the help of mediation from the Organization for Security and Co-operation in Europe (OSCE).
The rebels signed on to the ceasefire Friday after some deliberation.
Yet mortar and artillery fire has continued unabated without claiming any lives.
"Our positions came under attack 33 times since early Sunday," the Ukranian military said in a statement.
Such weapons have been banned by a February 2015 peace agreement that both sides have long ignored.
Kiev and its Western allies view the eastern separatists as Russian proxies who have been fighting for 31 months to destabilise the Ukrainian government and keep it dependent on the Kremlin's whims.
Moscow denies interfering in the conflict but international monitors have seen tanks and other heavy military equipment enter the Ukrainian war zone from Russia throughout the war.
March 2014 saw Russia annex Ukraine's Crimea peninsula in apparent retaliation for Kiev's ouster of the Moscow-backed president the preceding month.
Details are disputed but Kiev appears to have won back control of most regions around the town after an initial rebel assault.
Kiev lost eight soldiers in the battles while the rebels stuck their custom of not disclosing their deaths.
Ukranian General Anatoliy Petrenko -- charged with military contacts with his counterpart from Moscow -- told the Ukrainska Pravda website that he had asked the militias to stop their assault on Kiev-held villages near Debaltseve more than 800 times.
Debaltseve itself has been under separatist control since an immense January 2015 battle prompted Germany and France to step in and force all sides to agree to a peace deal the following month.
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