While the Netherlands beat Belgium 4-2 in a penalty shoot-out after both the teams were locked 2-2 at the end of the regulation time, World Cup bronze medallists Argentina defeated England 2-1 in another match.
While the Netherlands will face Argentina in the fifth-sixth place classification match tomorrow, England and Belgium will square up against each other to avoid the wooden-spoon.
In the first classification match, the Netherlands took a 2-0 in the first half through two field goals from Jeroen Hertzberger (11th minute) and Sander Baart (30th) and looked well set for a victory.
But Dutch custodian Jaap Stockmann, who was brought into the match for the shoot-out, made crucial saves to deny Cosyns and Florent van Aubel to register the win for the Netherlands.
In the second classification match of the day, Argentina eked out a hard-fought 2-1 win over England.
Drag-flick specialist Gonzalo Peillat (25th, 48th) converted two penalty corners in the second and fourth quarter for Argentina after Ashley Jackson (12th) gave England the lead from a penalty corner.
