The 29-year-old socialite has ended months of speculation about her marriage by filing papers in Los Angeles Superior Court on December 13, reported People magazine.
The couple, who tied the knot in 2009, had been living apart for several months amid Odom's drug use and cheating reports.
Khloe has not been photographed with her wedding ring since November 23, and has hinted at heartbreak in several recent posts on Instagram and Twitter.
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