Maxwell made short work of the 164-run target by blasting 44 off just 20 balls as Kings XI cruised to victory with six balls to spare.
His unbeaten 79-run stand with David Miller (30 off 27) took the game away from the opposition in front of a packed Holkar Stadium.
Maxwell's fireworks came after Ben Stokes led Rising Pune Supergiant's recovery with a blistering 50 off 32 balls, helping his team post 163 for six.
It was the first loss this season for Pune, who had beaten Mumbai Indians in their tournament opener on Thursday.
With Kings XI 73 for two in 10 overs and needing another 91 for victory, the match was hanging in balance. Then Maxwell came and ran away with the match with some brutal hitting.
The Australian, made captain of the side ahead of established names like Eoin Morgan, hammered four sixes and as many fours to begin his IPL campaign in style.
The Australian even did not spare Pune's most impressive bowler Imran Tahir, hitting him for consecutive sixes in the 16th over that virtually sealed the match in Kings XI's favour.
Earlier, after the fall of the top order that left Pune at 49 for three in the ninth over, Stokes showed why he commanded a Rs 14.5 crore price at the auction. He got good support from Manoj Tiwary (40 off 23).
Tiwary and Daniel Christian, who both remained unbeaten, took Mohit and Sandeep Sharma to the cleaners at the end of the innings, collecting 30 off the last 12 balls.
Sandeep castled Mayank Agarwal with a sharp inswinger though the shot selection of the opener so early on in the innings was questionable.
It was a memorable IPL debut for Tamil Nadu pacer T Natarajan, who took just two balls to strike, having the seasoned Ajinkya Rahane (19) holed out at deep cover.
The onus was on in-form captain Steven Smith (26) to bail his team out of trouble. He hung around for a while before he mistimed one to be caught at deep square leg.
Stokes was joined by Tiwary and together they scored 61 off 37 balls to set up a competitive total.
The Englishman slammed three sixes and couple of fours in his blazing knock.
Tiwary was not far behind with three fours and two sixes and ended up having a better strike rate than Stokes.
Christian hammered Sandeep for couple of fours and a maximum in the 20th over to push the score beyond 150.
Disclaimer: No Business Standard Journalist was involved in creation of this content
You’ve reached your limit of {{free_limit}} free articles this month.
Subscribe now for unlimited access.
Already subscribed? Log in
Subscribe to read the full story →
Smart Quarterly
₹900
3 Months
₹300/Month
Smart Essential
₹2,700
1 Year
₹225/Month
Super Saver
₹3,900
2 Years
₹162/Month
Renews automatically, cancel anytime
Here’s what’s included in our digital subscription plans
Exclusive premium stories online
Over 30 premium stories daily, handpicked by our editors


Complimentary Access to The New York Times
News, Games, Cooking, Audio, Wirecutter & The Athletic
Business Standard Epaper
Digital replica of our daily newspaper — with options to read, save, and share


Curated Newsletters
Insights on markets, finance, politics, tech, and more delivered to your inbox
Market Analysis & Investment Insights
In-depth market analysis & insights with access to The Smart Investor


Archives
Repository of articles and publications dating back to 1997
Ad-free Reading
Uninterrupted reading experience with no advertisements


Seamless Access Across All Devices
Access Business Standard across devices — mobile, tablet, or PC, via web or app
