The hydrogen indicates water bound to minerals in the ground, NASA said.
In the "Marias Pass" region, Curiosity successfully used its drill to sample a rock target called "Buckskin" and then used the camera on its robotic arm for multiple images to be stitched into a self-portrait at the drilling site.
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In drives on August 12, 13, 14 and 18, it progressed 433 feet (132 meters), bringing Curiosity's total odometry since its August 2012 landing to 11.1 kilometres.
Curiosity is carrying with it some of the sample powder drilled from Buckskin. The rover's internal laboratories are analysing the material.
The mission's science team members seek to understand why this area bears rocks with significantly higher levels of silica and hydrogen than other areas the rover has traversed.
Silica, monitored with Curiosity's laser-firing Chemistry and Camera (ChemCam) instrument, is a rock-forming chemical containing silicon and oxygen, commonly found on Earth as quartz.
Hydrogen in the ground beneath the rover is monitored by the rover's Dynamic Albedo of Neutrons (DAN) instrument.
It has been detected at low levels everywhere Curiosity has driven and is interpreted as the hydrogen in water molecules or hydroxyl ions bound within or absorbed onto minerals in the rocks and soil.
"The ground about 1 meter beneath the rover in this area holds three or four times as much water as the ground anywhere else Curiosity has driven during its three years on Mars," said DAN Principal Investigator Igor Mitrofanov of Space Research Institute, Moscow.
DAN first detected the unexpectedly high level of hydrogen using its passive mode.
Later, the rover drove back over the area using DAN in active mode, in which the instrument shoots neutrons into the ground and detects those that bounce off the subsurface, but preferentially interacting with hydrogen.
The measurements confirmed hydrated material covered by a thin layer of drier material.
Curiosity initially noted the area with high silica and hydrogen on May 21 while climbing to a site where two types of sedimentary bedrock lie in contact with each other.
Such contact zones can hold clues about ancient changes in environment, from conditions that produced the older rock type to conditions that produced the younger one.
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