"Diana: Her Fashion Story", hosted in her London residence Kensington Palace, follows her evolution from the demure outfits of her first public appearances to the glamorous gowns of her later life.
The show charts how she not only rewrote the rules of royal dressing with a more informal style but also expressed herself through her fashion choices, before her 1997 death in a car crash in Paris.
Curator Eleri Lynn said: "We see her growing in confidence throughout her life, increasingly taking control of how she was represented".
Some of the highlights include the discreet pale pink Emanuel blouse she wore for her engagement portrait in 1981 and the dazzling ink blue Victor Edelstein velvet dress she wore when she danced with John Travolta at the White House in 1985.
So iconic is the "Travolta" dress that it sold for USD 310,000 at auction three years ago.
Tiny fingerprints believed to belong to one of her sons -- Prince William and Prince Harry -- have been found on the material, preserved through the last 30 years.
The show will also highlight how throughout her years as one of the world's most photographed women, Diana revealed herself to be a diplomatic dresser.
The "Gold Falcon Gown" is a perfect example.
She wore the Catherine Walker cream silk dress embroidered with gold falcons -- the national bird of Saudi Arabia -- during a visit to the country in 1986.
She developed a more informal "working wardrobe" of chic Catherine Walker suits and tailored shift dresses to champion the causes she cared about.
These outfits, designed to convey approachability, she wore on charitable outings including meeting people with HIV and visiting children in hospital.
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