Young de Kock batted splendidly upfront scoring a 121-ball-135 studded with 18 fours and three sixes as he added 152 runs for the opening stand with Hashim Amla, who scored a patient 65.
The foundation laid by de Kock helped De Villiers and Duminy to launch a furious assault on the Indian attack as 135 runs were scored of the last 10 overs of the innings.
The Indians lost control from the start of the final 10 overs as Ravindra Jadeja (0/58 in 8 overs) leaked 17 runs.
The inexperience of new ball bowlers Mohit Sharma (0/82 in 10 overs) and Bhuvneshwar Kumar (0/68 in 9 overs) was evident as the South African batsmen played them with consummate ease.
There was a flurry of boundaries from their bats as the duo hit seven fours and one six in the first nine overs. That one six was hit by Amla off Bhuvneshwar Kumar, a huge hit into the electronic score-board and at the end of the ninth over, the two batsmen had put on 53 runs at an encouraging run-rate of 5.88.
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