The all stock deal, approved by the boards of both companies, would see Samsung's de facto holding company Cheil Industries -- which has interests from fashion to theme parks -- acquire general trade and construction affiliate Samsung C&T.
The merger, which is expected to be completed by September pending shareholder approval, will see Cheil offer 0.35 new shares for each Samsung C&T share.
The two companies are both listed on the Seoul stock market, with Cheil valued at 22 trillion won (USD 2 billion) and Samsung C&T 8.6 trillion won as of Tuesday morning.
"The two companies expect to create synergy by combining their construction businesses, while Samsung C&T's global network will help develop new opportunities overseas for Cheil's fashion, resort and catering businesses," the statement said.
Share prices of both Cheil Industries and Samsung C&T soared by the daily limit of 15 percent on Tuesday.
Today's announcement was the latest in a series of moves apparently aimed at solidifying the Lee family's grip on the sprawling behemoth.
The Lee family controls the vast Samsung Group via a complex web of cross shareholdings across the group's subsidiaries, including Cheil, where J.Y. Lee has a controlling stake.
Samsung C&T has a four percent stake in Samsung Electronics -- the group's flagship unit and the world's top maker of smartphones and mobile phones.
The Lee family currently has a less than five percent stake in Samsung Electronics, a holding that will be boosted by the merger.
Recent health problems concerning the senior Lee, currently bedridden after suffering a heart attack last year, prompted the group to step up restructuring efforts.
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