"Yesterday, we arrested some NATO spies... They will be exchanged for our own prisoners. I don't see any other way they will be freed," Denis Pushilin, the head of the insurgents' self-declared Donetsk Republic, told reporters.
Pushilin was speaking in front of the SBU security services building in rebel-held Slavyansk, where the OSCE team was being held.
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Late Friday, German Defence Minister Ursula von der Leyen confirmed that pro-Russian separatists had arrested 13 mission members, including the observers, their interpreter and driver. Four of the team are Germans, including three members of the German military.
Washington called for the immediate release of the OSCE team and State Department spokeswoman Jen Psaki insisted "there is a strong connection between Russia and these separatists".
The interior ministry in Kiev said that the OSCE observers were stopped at a rebel-held checkpoint as they were entering Slavyansk on Friday and were taken to the SBU building.
The Organisation for Security and Cooperation in Europe told AFP in Vienna, where it is based, that all the observers in its main mission on the ground in Ukraine were accounted for.
However, the detained group appears to be part of a separate, smaller unarmed military verification mission under German command.
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