Yuki, who had qualified for the main draw of the ATP 500 tournament, was leading 7-5 2-0 when American Stefan Kozlov opted out of contest due to viral illness.
However, another Indian qualifier, Ramkumar Ramanathan bowed out after a 4-6 1-6 defeat against Argentina's Guido Pella in the opening round.
Talking about his clash against showman Monfils, Yuki was highly motivated to take on a quality player.
"He is the defending champion and a class player. I have nothing to lose," said the 25-year-old Delhi lad.
Rohan Bopanna is competing in the doubles with American partner Donald Young. The wild card entrants are up against Daniel Nestor and Aisam-ul-Haq Qureshi.
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