The news comes as a heartbreak for their fans and shippers but definitely not a shock because the rumours of problems between the couple have been there for past few months.
According to TMZ, the 41-year-old actress filed the legal documents on Monday and has asked for physical custody of the couple's six children.
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Jolie is not asking for spousal support. She has listed the date of separation as Sept. 15, 2016.
One of the most celebrated Hollywood couples, Jolie-Pitt tied the knot in August 2014 after 10 years of togetherness.
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