The 41-year-old star has not disclosed the name of the charity she will hand over the funds to, reported FemaleFirst.
It is also been said that Jolie may give the collected amount to the UN Refugee Agency, of which she is a Special Envoy or the Preventing Sexual Violence Initiative.
The scent has been named, "Notes of a Woman" and Jacques Guerlain's spokesperson said, "We create perfumes for the women we admire."
The perfume endorsement is Jolie's first huge campaign since she filed for divorce from Brad Pitt.
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