Asin would represent colour, skincare products and support Avon's philanthropic efforts, the company said in a statement.
The company, a leading global beauty company with nearly USD 11 billion revenue, also launched a new range of make-up collections today.
Avon India Managing Director Ujjawal Mukhopadhyay said, "She (Asin) is an inspirational example of woman who embodies beauty both inside and out that makes her a perfect fit for Avon.