Bopanna and Mergea lost to Peya and Soares 6-4 1-6 8-10 in just an hour and two minutes yesterday in the 1.5 million euro tournament on the indoor courts of the St Jakobshalle.
Bopanna and Mergea had earlier made a first round exit from Vienna Open last week.
Bopanna and Mergea started off well and broke their rivals once to pocket the opening set.
The decider went to the super tie-break, where Peya and Soares kept their nerves to clinch the encounter and avenge their loss in the Stuttgart Open final in June.
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