Bopanna is back with his regular partner Pablo Cuevas for this tournament and they face Serbian team of Djokovic and Victor Troicki.
Paes, who has also been struggling to play with one partner consistently this season, has teamed up with Argentine Del Porto and they open their campaign against Luxembourg's Gilles Muller and American Sam Querry.
World number 26 Querry is in red hot form as he beat Rafael Nadal in the final to win ATP 500 event Acapulco last week.
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