The informal "high ambition coalition", announced by the European Union during the 195-nation conference in Paris this week, includes more than half of the countries of the world but is not a formal negotiating bloc.
Nevertheless, the alliance is calling for a legally binding, fair, durable agreement in Paris that must set a long-term goal, be reviewed every five years and include a system for tracking progress.
Brazil is the first major emerging economy to join the group.
"Brazil proudly supports the high ambition coalition and pledges our political support to this effort."
As the talks in Le Bourget on the northern outskirts of Paris lurch into overtime, decisions taken on a handful of core issues may determine whether it is seen as being up to the task of tackling climate change.
The latest draft accord, still open to change, says its purpose is to hold temperatures to well below two degrees Centigrade above pre-Industrial Revolution levels. But it also says nations should aim for 1.5C, a target backed by the new grouping.
Other key issues yet to be decided include how often to review and strengthen national carbon gas-cutting pledges, and when to start doing so.
Among the major players absent from the so-called high ambition coalition are India and China. India in particular has balked at moving toward the higher end of the spectrum on all these goals.
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