"As long as independence has not been proclaimed, and if (Catalan leader Carles Puigdemont) backs down, there is room to manoeuvre," Fernando Martinez-Maillo, number three in the conservative Popular Party of Prime Minister Mariano Rajoy, told Cadena SER radio.
Until Spain's Senate convenes to discuss the government's move to start imposing direct control over Catalonia -- likely by the end of October -- Puigdemont "can change course, can return to constitutional legality," Martinez-Maillo said.
Puigdemont has since been threatening to declare an independent Catalan state, which Madrid bitterly opposes.
Rajoy's government said it would push ahead with steps to seize some of the regional government's powers in semi- autonomous Catalonia after giving Puigdemont until Thursday to back down.
Puigdemont retorted that any such move to impose direct rule - in a region where even Catalans who oppose independence value their autonomy highly -- could result in a unilateral declaration of independence by local lawmakers.
Puigdemont says he has a mandate to declare independence after the referendum, which his administration says resulted in a 90 percent "Yes" vote.
But turnout was given as only 43 per cent as many Catalans who back unity stayed away from the vote.
Spain's Constitutional Court had ruled the referendum illegal and voting day saw a heavy crackdown by police who used batons and rubber bullets against voters in some places.
Rajoy's conservatives are working with opposition Socialists and centrists on the Catalan crisis under a "national unity pact" as they seek to avoid the break-up of Spain.
"The prestige of our rule of law is at stake," Carmen Calvo, the Socialists' chief negotiator with the government, told public television.
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