Speaking to Capital FM, Brown, 26, said he would love to team up with Malik whom he called his "homeboy," reported Aceshowbiz.
"Zayn, yeah, my homeboy. We're on the same label now. Of course, of course, (I'd work with him) I don't shy away from anyone, and I think he's a great artist.
"Now he's doing his solo thing, I know he has a huge fan base and the fans are waiting to hear his stuff, so it would be cool to get down and collaborate," he said.
"Hi @zaynmalik I have beautiful instruments and you have a voice lets figure this out my guy. Epic album cuts tho no radio singles," he wrote.
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