"We can confirm 4 members of our Donetsk-based team are now released after 32 days in captivity," the OSCE Special Monitoring Mission to Ukraine said on its Facebook page.
Two groups of unarmed observers from the Vienna-based European security organisation totalling eight international monitors and a Ukrainian translator were detained at roadblocks three days apart in late May.
Separatist leaders had on Thursday freed the group they had detained on May 26 in the Donetsk region.
A Donetsk rebel spokeswoman told AFP that the second team would be presented to reporters at a local hotel later on Saturday.
Russian President Vladimir Putin publically called on the pro-Kremlin militia to free all people held against their will under the terms of a temporary ceasefire in the nearly three-month insurgency agreed with Kiev at the end of last week.
Ukrainian President Petro Poroshenko extended the truce today morning until 1900 GMT on Monday.
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