The Russian Foreign Ministry issued a statement condemning what it described as a sharp escalation in the violence in eastern Ukraine, accusing the Ukrainian government of using the talks as cover for military operations against its citizens.
The fighting began when forces loyal to the Kiev government moved in to protect a television tower near the small village of Andriyivka.
Debris from the shooting was visible, including a badly damaged train and craters caused by mortar bombs or other heavy artillery.
Government forces in recent weeks have achieved only limited results in quashing the pro-Russia groups that have declared independence for Ukraine's eastern Donetsk and Luhansk regions.
Polls have shown, however, that a majority of eastern Ukrainians support a united country, although most are too fearful of the armed separatists to say so publicly.
In one southeastern city, Mariupol, steelworkers retook government buildings from pro-Russia fighters and cleared away their barricades.
Mariupol is a major industrial city in the Donetsk region, lying on the main road between Russia and the Crimean Peninsula, which Russia annexed in March.
Other similar and apparently unaccountable groups look to be emerging elsewhere in the chaotic east.
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