The 25-year-old BJP-Shiv Sena alliance had split on September 25 over the issue of seat sharing for October 15 assembly elections.
Chavan had resigned after his government was reduced to a minority as the ally NCP withdrew the support.
"After the withdrawal of support by NCP to the Democratic Front government on 25th September, the government has become a minority government," the letter written yesterday by the Governor to senior Sena leader Subhash Desai read.
Rao further said that if both parties fail to respond to his letter, it shall be deemed that the parties are not willing or able to form the government.
Reacting to the Governor's letter, Sena leader Subhash Desai said the party will form a government only when it comes to power with a majority post elections.
"Yes, the Governor did send me a letter asking us if we would like to form the government. I categorically told him that he does not need to come to us. We will ourselves go to him, but only after we win the elections with a majority," Desai told PTI.
Rao, a senior BJP leader from Telangana, was appointed Governor of Maharashtra last month, after K Sankaranarayanan resigned from the post following his transfer to Mizoram.
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