Ageing survivors, relatives, government officials and foreign delegates were to observe a moment of silence at 8:15 am local time (0445 IST Tuesday), the time of the detonation which turned the city into a nuclear inferno.
An American B-29 bomber named Enola Gay dropped an atomic bomb on August 6, 1945, in one of the final chapters of World War II. It killed an estimated 140,000 by December that year. Three days later, the port city of Nagasaki was also bombed.
Japanese officials later today will be unveiling Tokyo's biggest-ever naval ship in peacetime, as the government moves to beef up Japan's self-defence forces, jangling nerves in neighbouring China and South Korea.
Tokyo insisted the timing of an annual peace ceremony and the helicopter carrier was coincidental.
Among the attendees in Hiroshima last year was Clifton Truman Daniel, grandson of former US president Harry Truman, who authorised the bombings. He was the first Truman relative to attend the annual anniversary in Japan.
Anti-nuclear sentiment flared in Japan after an earthquake-sparked tsunami left some 19,000 dead or missing and knocked out cooling systems at the Fukushima Daiichi nuclear plant two years ago.
Meltdowns at the crippled site spread radiation over a large area and forced thousands to leave their homes in the worst atomic disaster in a generation.
Abe's conservative Liberal Democratic Party has also said it wants to upgrade Japan's self-defence forces into a full-fledged military, which would mean overhauling a pacifist constitution imposed on the country by the US and its allies after WWII.
Later today, the forces' naval arm was due to hold a ceremony marking the launch of a 248-metre (810-foot) helicopter carrier which can accommodate nine aircraft.
Officials said the ceremony was scheduled for the same day as the Hiroshima anniversary due to favourable ocean tides and an auspicious date.
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