According to police, the man, identified as Sura Behera, was asked by his wife to take their daughter, who was suffering from fever, to hospital when, in a fit of rage, he allegedly threw acid.
His two wives, four daughters and father-in-law sustained burn injuries and had to be hospitalised, the police said.
Behera was arrested but he denied the charge, alleging that his father-in-law Banamali Behera threw the acid on his wives and daughters.
Investigations are underway, police said, adding, family dispute is suspected to be reason behind the crime.
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