The Sensex succumbed to the pressure, ending down 10.11 points, or 0.04 per cent, at 26,633.13.
The gauge had gained 47.79 points previously.
The NSE Nifty too closed in negative territory with a minuscule fall of 1.75 points, or 0.02 per cent, at 8,190.50.
Sentiment soured after services PMI contracted for the second straight month and the all-crucial GST meet remained deadlocked over dual control, compensation and high-sea taxes.
The upcoming corporate results season and the approaching Union Budget kept investors on their toes.
The Nikkei India Services Purchasing Managers' Index (PMI) stood at 46.8 in December, little changed from November's 46.7, a proof that demonetisation is taking its toll on the services sector.
The rupee struck a contrarian tone, strengthening 28 paise to end at 68.05.
In Europe, Frankfurt's DAX fell 0.17 per cent, Paris CAC 0.01 per cent and London's FTSE 0.03 per cent as investors waited for inflation figures for the euro zone.
RIL slumped 1.99 per cent, ICICI Bank 1.26 per cent and Cipla 1.05 per cent.
However, Bharti Airtel, Bajaj Auto, Wipro, Tata Motors, Hero Motocorp and Asian Paints ended in the green, rising by up to 3.47 per cent.
Banking index dropped, along with oil and gas, PSU and metal.
The broader markets threw up a mixed picture, with small-cap jumping 0.47 per cent and mid-cap declining 0.09 per cent.
Hong Kong shares declined 0.07 per cent while Japan's Nikkei rose 2.51 per cent and Shanghai gained 0.73 per cent.
of five states, which could be a litmus test for the government following the demonetisation move and accordingly the market sentiment will deviate," added Nair.
Out of 30 Sensex stocks, a total of 16 went up and 14 closed down.
The market breadth remained positive as 1,614 stocks ended higher, 1,182 declined while 126 remained unchanged.
The total turnover on BSE declined to Rs 2,608.67 crore, from Rs 2,621.40 crore yesterday.
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