The planet reflects much less sunlight than the Moon, on which surface darkness is controlled by the abundance of iron-rich minerals that are known to be rare on Mercury's surface, researchers said.
Scientists had earlier proposed that Mercury's darkness was due to carbon that gradually accumulated from the impact of comets that travelled into the inner solar system.
Researchers led by Patrick Peplowski of the Johns Hopkins University in US have confirmed that a high abundance of carbon is present at Mercury's surface.
The researchers obtained data from NASA's MESSENGER (MErcury Surface, Space ENvironment, GEochemistry, and Ranging) spacecraft, the first space mission designed to orbit Mercury.
"We used MESSENGER's Neutron Spectrometer to spatially resolve the distribution of carbon and found that it is correlated with the darkest material on Mercury, and this material most likely originated deep in the crust," said Larry Nittler, from Carnegie Institution of Washington.
MESSENGER obtained its data via many orbits on which the spacecraft passed lower than 100 km above the surface of the planet during its last year of operation.
Neutron Spectrometer measurements showed higher amounts of low-energy neutrons, a signature consistent with the presence of elevated carbon, coming from the surface when the spacecraft passed over concentrations of the darkest material.
Graphite has the best fit to the reflectance spectra, at visible wavelengths, and the likely conditions that produced the material, researchers said.
When Mercury was very young, much of the planet was likely so hot that there was a global "ocean" of molten magma.
Scientists have suggested that as this magma ocean cooled, most minerals that solidified sank, except graphite, which would have been buoyant and floated to form the original crust of Mercury.
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