The 25-year-old Brazilian arrived in the French capital on Friday after his world-record 222-million-euro move from Barcelona.
The forward will be presented to fans before tomorrow's match, but said he could play a part, despite having not yet spoken to PSG coach Unai Emery.
"I always want to play, so I am ready to do so tomorrow," Neymar said at his unveiling today.
"I have trained in pre-season. I stopped for two days, but I am ready, I've seen the pitch and I want to put the PSG shirt on and play."
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