US benchmark West Texas Intermediate for October delivery was up 11 cents at $94.66 while Brent crude for October advanced 24 cents to $102.70 in mid-morning trade.
Ukraine and the West yesterday said that Russian troops are actively involved supporting pro-Kremlin separatists who have been fighting against Kiev's rule since April.
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The United States warned it was considering new sanctions against Russia over the latest development.
Desmond Chua, market analyst at CMC Markets in Singapore, said fresh sanctions 'may then trigger further retaliatory measures that would weigh on the euro bloc'.
The intensified standoff between the neighbours, seen as the worst East-West crisis since the end of the Cold War, has sparked fears of a full-fledged war.
Such a development could cause energy prices to surge as Russia is the world's number-two oil producer, and Ukraine is a key conduit for Moscow's gas exports to Europe.
Stronger-than-expected US economic growth data meanwhile raised hopes for stronger demand in the world's largest oil consumer.
The US Commerce Department yesterday said the country's economy expanded at an annual rate of 4.2% in the second quarter, revising upward its July estimate of 4.0%.
Chua said the latest figure has placed the world's biggest economy "on track for growth forecasts which could spur a quicker pace of (monetary) tightening".
The US Federal Reserve has previously signalled that it will only hike interest rates late next year, but market watchers say robust US economic data could shorten the central bank's timetable.
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