Zimbabwe also maintained their unbeaten run in Group B and progressed to the next stage with an 89 runs victory over Hong Kong.
In front of broadcast cameras and nearly 2,000 spectators at the Harare Sports Club here, Powell scored a dazzling less than run-a-ball 101 with seven fours and as many sixes to lift the Windies from 83 for five to 257 for eight. He featured in an 86-run sixth-wicket partnership with captain Jason Holder, who hit three fours and a six in a 71-ball 54.
West Indies fast bowler Kemar Roach then picked up two early wickets of Paul Stirling (18) and Andrew Balbirnie (9) and then returned to dismiss the dangerous looking Ed Joyce (63, 86b, 7x4s) and Kevin O'Brien (38) in a space of four deliveries to finish with figures of 10-3-27-4 as Ireland slipped from 166-4 to 205 all out in 46.2 overs.
Kesrick Williams too did his part as he got rid of the lower-order batsmen, taking four for 43 in 8.2 overs.
Roelof van der Merwe starred in the Dutch victory when he contributed 33 in his side's 216 for eight and then returned figures of 10-0-46-4 as PNG were dismissed for 159 in 42.1 overs.
This result means Monday's matches between the Netherlands and the West Indies, and Ireland and the United Arab Emirates will decide which two sides will join the two-time former world champions in the Super Six.
Hong Kong's Anshuman Rath fought a lone battle scoring 85 but wickets continued to fall at the other end until the Asian side was bowled out for 174 in 46.5 overs.
Sikandar Raza was the most successful bowler with three for 30, while Kyle Jarvis, Graeme Cremer and Sean Williams took two wickets apiece.
Hong Kong's defeat also gave a lifeline to Afghanistan, who defeated Nepal by six wickets after Mohammad Nabi took four for 33 and then scored 34 in their last group match. They will now await the result of the Hong Kong versus Nepal match to know their fate.
If Nepal beat Hong Kong on Monday, Afghanistan, Hong Kong and Nepal will be tied on one win apiece, then the side with the better net run-rate will go through. After today's matches, Afghanistan has a net run-rate of +0.038, Hong Kong is on -1.26 and Nepal are -1.54.
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