Six people were arrested for offences ranging from forcibly entering government property and public disorder to assaulting an officer, police said in a statement yesterday.
Around 150 people pushed into the grounds of the complex, some scaling over a tall exterior fence, as others outside yelled "open the gates".
Police repeatedly used pepper spray on the protesters, who used umbrellas, surgical masks and goggles to protect themselves, an AFP reporter at the scene said.
Student groups are spearheading a civil disobedience campaign along with democracy activists in a days-long protest at Beijing's announcement last month that it would vet who can stand for Hong Kong's top post of chief executive at the next election.
By early today, around 1,000 people were outside the Southern Chinese city's main government complex. Numbers had earlier swelled to more than 2,000 as secondary school pupils, some wearing uniforms, joined the university students.
Early today, a government statement had "expressed regret" that protesters had stormed the complex, saying security personnel, police officers and protesters had suffered injuries but without giving details.
"We don't care if we get hurt, we don't care if we get arrested, what we care about is getting real democracy," protester Wong Kai-keung said from the front line of the charge.
Then on Thursday night, more than 2,000 people took their protest to the residence of Hong Kong leader Leung Chun-ying with the hope of speaking to him. Leung has so far refused to speak to the students or meet their leaders.
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