Put into bat, India lost a couple of early wickets after opener Shikhar Dhawan (11) and Virat Kohli (0) were scalped by Chris Woakes (4-52) with India reeling on 19 for two.
But Rohit Sharma (52) and Ajinkya Rahane (41) batted sensibly to lay a solid foundation for the middle-order to build upon.
Raina, registering his fourth ODI ton, then came good in the batting powerplays with Mahendra Singh Dhoni (52 off 51 balls) as his able partner put on a 144-run fifth-wicket partnership to propel India to a challenging score.
Raina's knock was laced with 12 fours and 3 sixes but finally the aggressive left-hander fell to Woakes in the 47th over.
Dhoni, hitting 6 boundaries, took over from Raina to register his 55th half-century of his ODI career but was finally cleaned up by Woakes.
In the end Ravichandran Ashwin (10 not out) and Ravindra Jadeja (9 not out) managed 13 runs in the final over to help India cross the 300-run mark.
England pace spearhead James Anderson (0-57), Chris Jordan (0-73), Ben Stokes (0-54) and Joe Root (0-14) went wicketless in the innings.
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