Zinedine Zidane's side are chasing a third successive European title and fourth in five seasons after demolishing Italian champions Juventus 4-1 in Cardiff in June.
The record 12-time European champions will also take on APOEL of Cyprus in a testing Group H.
World record signing Neymar and Paris Saint-Germain were paired alongside Bayern Munich, with Scottish champions Celtic and Belgian outfit Anderlecht completing the line-up in Group B.
Chelsea, one of a record five English teams to qualify for the group phase, will meet Atletico Madrid in Group C as well as Roma and Qarabag, the first side from Azerbaijan to reach this stage of the competition.
Pep Guardiola's Manchester City are in Group F alongside Ukrainian champions Shakhtar Donetsk, Napoli and Feyenoord while Liverpool will play Spartak Moscow, Sevilla and Maribor in Group E.
French champions Monaco, who reached last season's semi- finals, face Porto, Besiktas and debutants RB Leipzig in Group G.
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