The mafia boss, Alexander Matusov, was arrested on Monday in front of a supermarket in Thailand's eastern seaside town of Sattahip in Chonburi province, said Police Gen Wut Liptapanlop.
Matusov's network "Chelkovo" was active from 1995 to 2009 and was notorious for killings, extortion and kidnaps in Moscow and St Petersburg areas, according to Alexey Falunin, a Russian diplomat in Bangkok.
"They were responsible for a lot of killings and his detention is very important to us," he told The Associated Press.
Wut said the 52-year-old first entered Thailand in 2009 and left before returning on a fake Armenian passport. He said Matusov had been living in Thailand on a retirement visa.
Thai immigration police had revoked his visa and were pushing for his deportation to Russia for prosecution.
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