Ora, 22, took to social-networking site Instagram to share the news with fans, reported E! online.
"Joining forces with Madonna and Lola!. It's official Ritabots - I'm the new face of Material Girl!," she wrote.
Madonna and her daughter Lola, 16, also released a statement saying, "Rita is a talented beauty but what really drew us to her is the confidence she oozes through her music and her unique sense of style. On stage or off, in photos or on the street - she's a magnet! This is what the Material Girl brand is all about."
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