In a statement, St Louis County executive Steve Stenger said county police would immediately take charge of "police emergency management" in Ferguson and surrounding districts.
"In light of last night's violence and unrest in the city of Ferguson, and the potential for harm to persons and property, I am exercising my authority as county executive to issue a state of emergency, effective immediately," he said yesterday.
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Tyrone Harris is accused of first-degree assault on police officers, armed criminal action and shooting at a motor vehicle, St Louis County police said.
Harris, from Northwoods, another section of St Louis County, remained in hospital yesterday with wounds sustained in the shootout.
Meanwhile, in St Louis city center, more than 50 protesters were arrested after climbing the barricade around a federal courthouse during a mid-day demonstration, local news media reported.
Sunday's gunfire followed the looting of at least two Ferguson businesses, on a commercial strip around the corner from where Brown fell.
"I think it's unfortunate that a beautiful day of events ended like that," said Dellena Jones, whose hair salon was among the shops hit.
"Some people broke in to some of the businesses on our lot, and so we are all here helping each other," she told AFP yesterday.
"We have not assessed anything," she added when asked the extent of the damages to her shop, which she said had been turned into "a wreck."
Attorney General Loretta Lynch strongly condemned Sunday's violence, as she spoke yesterday at a police union convention in Pittsburgh, Pennsylvania.
"Not only does violence obscure any message of peaceful protest, it places the community, as well as the officers who seek to protect it, in harm's way," she told the Fraternal Order of Police gathering.
St Louis County Police Chief Jon Belmar earlier said the shootout started when four plainclothes detectives in a van came under fire.
AFP video showed a black man lying facedown on the ground in handcuffs, bleeding profusely. Belmar declined to comment on the race of the detectives.
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