During her three-day visit, Swaraj will also have bilateral meeting with her Italian counterpart Paolo Gentiloni, the first high-level contact between the two countries after the UN tribunal's verdict of the return of Italian marines charged with murdering two Indian fishermen off Kerala coast in 2012.
"Leaving for Rome to attend the canonisation ceremony of Mother Teresa," Swaraj tweeted.
According to official sources, Swaraj will meet her Italian counterpart over the weekend during which the two sides will review the status of bilateral ties.
Unsatisfied with Indian judicial process, Italy moved the UN Tribunal, which in May this year allowed Girone to return pending the trial. Latorre is already in Italy on health grounds.
Apart from the central government delegation, two state government-level delegations from Delhi and West Bengal led by Chief Ministers Arvind Kejriwal and Mamata Banerjee respectively also left for Rome to attend the ceremony.
Swaraj's delegation will comprise Minister for Food Processing Industries Harsimrat Kaur Badal, Lok Sabha MPs Prof K V Thomas, Jose K Mani, Anto Anthony and Conrad K Sangma and Deputy Chief Minister of Goa Francis D'Souza.
Secretary (West) in the Ministry of External Affairs Sujata Mehta will also be part of the delegation.
In March, Pope Francis had announced that Mother Teresa, who founded the Missionaries of Charity, will be elevated to sainthood after the Church recognised two miracles attributed to her after her death in 1997.
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