The main opposition umbrella group attending the biggest effort yet to end the war called Russia's bombardment near Aleppo -- with 270 raids since Monday morning, according to monitors -- "unprecedented".
"Since last night a big massacre is taking place in Syria and nobody is doing anything. Nobody is saying anything, the international community is completely blind," said Salem al-Meslet from the High Negotiations Committee (HNC).
But chief government negotiator Bashar al-Jaafari shot this down today, saying the talks were still "in a preparatory phase", that the opposition had failed to even name its negotiating team and that there was no agenda.
"We are still in the preparatory phase for indirect talks ... We still don't know who the opposition delegation is," Jaafari told reporters after meeting de Mistura, the third UN envoy for Syria since the war began in March 2011.
However, Interfax later reported that Russian deputy foreign minister Gennady Gatilov said de Mistura would again meet the opposition negotiators "tomorrow or the day after tomorrow" and that they "will explain their position and will announce the makeup of the delegation that will participate in talks".
The HNC has demanded the regime allow humanitarian access to besieged towns, stop bombing civilians and release thousands of prisoners -- some of them children -- languishing in regime jails.
The Syrian Observatory for Human Rights, a monitoring group, said at least 18 civilians had been killed in the raids today, including five women, three children and two emergency workers.
"We have never seen things like this since the beginning of the revolution," HNC spokeswoman Basma Kodmani said, calling the air raids "unprecedented".
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