The delay appears to reflect the government's displeasure with the opposition's insistence that President Bashar Assad must leave at the start of any transitional period.
The United Nations is scheduled to resume the peace talks between the government and the Syrian opposition in the Swiss city today.
The opposition's delegation arrived yesterday, after publishing a communique last week that said it was ready for talks "without preconditions."
"I can confirm we have received a message from Government of Syria indicating that their delegation would arrive tomorrow," said Michael Contet, an adviser to UN Special Envoy to Syria Staffan de Mistura.
As in previous talks, a major point of disagreement between the two sides will be the future of Assad. The opposition's position is that Assad must leave at the start of any transitional period that will lead Syria out of nearly seven years of civil war.
Damascus has refused to negotiate over Assad's future in any talks with the opposition. It says it wants to focus on defeating "terrorism," its byword for armed opponents of the Syrian president.
The delegation was expanded last week under Saudi Arabian auspices to include opposition groupings seen by Damascus as more palatable for negotiations, including the so-called "Moscow group" which has resisted calling for Assad's departure.
Hariri said the reformulation removed any excuse by the government and its chief diplomatic backer, Russia, to circumvent the UN talks.
De Mistura stressed he would "not accept any preconditions by any party" to talks, and said the talks would be guided by a 2015 Security Council resolution mandating a political transition for Syria.
In Geneva, three diplomats said representatives of the five permanent UN Security Council members were meeting to discuss the talks that were set to begin later today with a meeting between de Mistura and the opposition.
The officials spoke on condition of anonymity because he was not authorised to speak publicly to the media.
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