The assailants -- five in number -- fled under the cover of darkness, said assistant sub-inspector M K Bhoir of Ganeshpuri police station.
The victims left the wine shop in Ambadi for their employer's house in Ambernath to hand over day's cash collection of Rs 7 lakh.
At around 10.15 pm, their vehicle was waylaid by a group of five men at Varet village who opened fire from pistols and then ran away, ASI Bhoir said.
The injured men -- Ashok Rangawani, Rajesh Ahuja and Vishal Manial -- were admitted to a hospital in Mulund.
Additional Superintendent of Police, Thane Rural Prashant Kadam visited the crime spot today.
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