"Iran has shown its readiness to engage with dignity and it's time for our negotiating partners to seize the moment and use this opportunity which may not be repeated," Zarif said, after meeting alone with US Secretary of State John Kerry.
He was speaking as exhausting, marathon talks again went into the evening on the seventh of negotiations in a luxury lakeside hotel in the Swiss city of Lausanne.
The US, Russia, China, Britain, France and Germany want Iran to scale down its nuclear programme to extend the "breakout" time needed for the Islamic republic to assemble enough nuclear material to make a bomb.
Iran denies wanting the bomb and its negotiators are under strict orders from supreme leader Ayatollah Ali Khamenei to refuse any curtailing of its programme without sanctions relief.
Zarif said his country wanted "an entente with the world but it will not accept submitting to force and will not accept excessive demands."
Global powers have always refused an immediate lifting of all sanctions in order to be able to swiftly put them back into place if Iran violates the deal.
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