The fiery co-leader of the pro-democracy Orange Revolution in 2004 announced her move in a letter read to some 20,000 supporters who thronged central Kiev yesterday.
Organisers expect thousands to turn out on Kiev's European Square today evening for a third straight day of protests against President Viktor Yanukovych's U-turn on the EU accord.
Sporadic clashes have marred the rallies in Kiev and more nationalist parts of western Ukraine, with riot police firing tear gas at demonstrators and protesters hurling street cones and rocks at security personnel.
"I am announcing an indefinite hunger strike demanding that Yanukovych sign an association and free trade agreement with the EU," said the jailed former prime minister.
"And if Yanukovych does not sign our agreement with the EU on November 29, wipe him off the face of Ukraine through peaceful and constitutional means."
Protesters have set up two dozen tents in central Kiev where they have been spending the night to make sure police do not close off the square where the largest demonstrations are being held.
Two top members of the European Parliament warned Ukraine on today that it faced "serious consequences" should police continue resorting to the use of force against protesters.
The latest crisis in the nation of 45 million was sparked by the government's abrupt decision to scrap the planned signature of a historic deal with the EU at a two-day summit in Vilnius starting Thursday.
The U-turn came shortly after Yanukovych held secret talks in Russia with President Vladimir Putin meant to address economic sanctions Moscow planned to slap on Kiev if it signed the EU pact.
The so-called Association Agreement with the EU would have put Ukraine firmly on the path to eventual membership and pulled it out of Russia's historical orbit.
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