An estimated 10,000 to 25,000 people are stuck in the city, the Islamic State group's main stronghold, said UN spokesman Stephane Dujarric, who noted that "exact figures remain difficult to verify due to the situation on the ground."
"Access to Raqa is not currently possible for the UN, due to the fighting on the ground," Dujarric said during his daily briefing.
"We remind all military actors of their obligations to protect civilians and ensure humanitarian access, in line with international humanitarian law."
The Syrian Democratic Forces, a Kurdish-Arab alliance backed by an international coalition battling IS, entered Raqa city two months ago.
But the force's progress has been hindered by IS which is fighting hard to hang on to the de facto Syrian capital of the "caliphate" it self-proclaimed in June 2014.
The SDF is backed by the US-led coalition battling IS in Iraq and Syria, which has supplied weapons, air cover and a limited number of troops.
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